Looking at the final clashes of the Champions League’s opening gameweek, we’re feeling like Goldilocks on her third bowl of porridge, this lot’s just right. It’s still early days, so the bookies are scratching their heads over some of the curveball fixtures this massive European tourney serves up. And honestly, we reckon they’ve saved the tastiest odds till last. And we’ve got an appetite, so let’s chow down on our goaltastic 2025/26 Champions League Gameweek 1 Thursday Acca Tips.
2025/26 Champions League Gameweek 1 Thursday’s Acca Odds
| Game | Market | Odds | Return on £10 |
|---|---|---|---|
| Man City vs Napoli | Haaland to Score Two or More Goals | 9/2 | £55.00 |
| FC Copenhagen vs Bayer 04 Leverkusen | Both Teams to Score – Yes | 7/10 | £17.00 |
| Galatasaray vs Eintracht Frankfurt | Over 2.5 Goals – Yes | 1/2 | £15.00 |
| Threefold Acca (All Three Games) | All Three Markets | 13.02/1 | £140.25 |
* Odds correct as of 10:12am 18/09/2025
We reckon each of these represents the absolute crème de la crème of Champions League odds this week. That said, they’re all from different games, so you’ve got a couple of choices. You can cherry-pick whichever looks best and back them individually, or go all in on the final set of matches from gameweek 1 with a barnstorming threefold acca, where a tenner could see you walking away with a tidy £140.25.
EXPIRING:
26/04/2026
2025/26 Champions League Gameweek 1 Thursday’s Acca Tips
Bet 1: Man City vs Napoli : Haaland to Score Two or More Goals? Brace Yourself for a Goal-Feast (9/2)
Let’s be honest, you hardly need us to tell you Haaland’s a goal-scoring machine. For the Norwegian phenom, the back of the net must feel so much like home he could hang a few family photos on the posts and stick the kettle on, all while the defenders are still trying to figure out what that round blur was that just whizzed past them.
Still, bagging two goals in any match, especially against a side like Napoli, is no easy feat. So, what do the numbers say? So far in the Premier League he’s netted five goals in four games, meaning a brace looks about 20% likely. Our odds converter calculator tells us that converts to 18.2%. On the surface, then, the bookies don’t look too far off.
But that hardly tells the full story. City haven’t exactly roared out of the gates this season, three wins from five is a strange look for them, but they seem to be finding their stride again following that 3-0 derby demolition of Manchester United. The cobwebs are gone, the momentum’s back, and there’s still a point to prove. Those goals were the trickle in an otherwise barren drought, and now the dam’s burst, you can bet plenty more are on the way.
And with a move to Barcelona looking more and more likely for Haaland, he’ll want to make this final European stint with City really count. Put simply, he’ll be hungrier than a seaside seagull for goals, and when his appetite’s up, more often than not, he feasts.
All told, we’d put his chances of bagging a brace closer to 30–35%, which makes this a cracking mid-risk value bet.
Bet 2: FC Copenhagen vs Bayer 04 Leverkusen: Both Teams to Score? Odds Say Yes, Stats Say Absolutely (7/10)
We love a low-risk bet to anchor our acca, and this one’s an absolute peach – no need to keep the numbers boffins burning the midnight oil, the maths here is dead simple. Across the last five games each, nine out of 10 have landed over 2.5 goals between FC Copenhagen and Bayer Leverkusen. That’s a 90% real probability staring you in the face, yet the bookies have it hovering just over evens.
Now, we tried to suss out what they’re playing at. Maybe someone at bet365 has a mole in the camp who reckons the lads have all left their boots at home. But we’re not buying it. One look at our goal stats confirms that both squads are stacked with attacking talent: Mohamed Elyounoussi, Jordan Larsson and Elias Achouri lighting up the Danish Superliga for Copenhagen, while Patrick Schick and Alejandro Grimaldo have been carving through defences like a Sunday roast for Leverkusen.
Factor in their similar overall quality and the way both sides love a risk, which usually leads to a proper back-and-forth ding-dong, and you’ve got every ingredient for both teams to score. Honestly, we’re baffled by the odds here. But here’s one thing we’re not confused about, these are some of the best value odds of the tourney so far.
Bet 3: Galatasaray vs Eintracht Frankfurt: Over 2.5? We’re Expecting Goals Galore (1/2)
We’re having serious déjà vu here. Just like in our previous bet, the stats are screaming that the bookies are off by double digits. Galatasaray have gone over 2.5 goals in five out of five games, and Eintracht Frankfurt in four of their last five. That leaves us just one short of a perfect 10 in recent form, which puts the true mathematical probability for this market at around 90%. Again.
The bookies have got a bit closer this time, 1/2 works out at 66.7%, but they’re still more than 20 percentage points shy of a little town we like to call “making any sense”. And we can’t spot any outliers to explain it. Burkardt, Osimhen, Icardi, Uzun and the other big hitters are all ready to go. Plus, both sides have a decent shot at winning their opening clash, which should make for a proper tit-for-tat affair. Bet365’s generosity, or sheer folly, we’re not sure which, is astounding. No wonder they’re one of the best bookmakers in the UK. We’d be on this faster than a roadrunner in rocket shoes, just in case they change their mind.
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